Hexane fire hazard rating

Hexane fire hazard rating


Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Acutely, the most common toxic effects are central nervous system depression and FIRE FIGHTING: Do not get water inside container. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Dangerous fire hazard when exposed to heat or flame. Decomposition under effect of heating (See also Section Hazardous decomposition products). direct sunlight and any area where the fire hazard may be acute. HARMFUL IF INHALED. The NFPA Diamond The NFPA Diamond. hmis(r*) iii, nfpa): this information is intended solely for the use of individuals trained in the particular system. IB. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. US. 4-EXTREME. Benzene. The use of explosion-proof electrical equipment is recommended. L. 0015- 23. Flammable liquid and vapor. Index-No. It is soluble in alcohol, ether, chloroform, and acetone, and insoluble in water. described in the OSHA's Hazard Communication Standard (HCS) 29 CFR 1910. "Fire hazard", "Immediate (acute) health hazard" SARA 313 Chemical Components CAS-No. 14. Store in a cool, dry well-ventilated location, away from direct sunlight and any area where the fire hazard may be acute. Water may be ineffective. 6 Classification of Flammable and Combustible Uquids . National Fire Protective Association: Health - 1, Flammability - 3, Reactivity - 0 NOTE: NFPA ratings use a numbering scale that ranges from 0 - 4 to indicate the degree of hazard. Both the liquid and the gas pose a serious fire hazard when accidentally released. Hexane and other volatile hydrocarbons (petroleum ether) present an aspiration risk. S. 64741-47-5. Advice on   North American hazardous locations classification in classes, divisions and groups. EPA CERCLA Hazard ous Substances (40 CFR 302) The Hazardous Materials Identification System (HMIS) is a numerical hazard rating that incorporates the use of labels with color developed by the American Coatings Association as a compliance aid for the OSHA Hazard Communication (HazCom) Standard. Whatever you need to store at any temperature, MEGS has the cryogenic solution that meets your needs. PAGE 1 OF 9 SAFETY DATA SHEET SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name (As Labeled) RC Musson 400 Chemical Name: Hexane / Toluene/Acetone Health Hazards and Protective Measures. In a fire  J. the use of water spray (fog) while effective, may cause frothing and foaming. 14 Special Hazard Gaseous Fire Extinguishing Agents . Vapors may accumulate in low or confined areas or travel a Jun 13, 2006 · Vapors are an explosion and poison hazard indoors, outdoors, or in sewers. 12:100-7) require employers to provide similar information and training to their employees. Hydrogen poses a serious fire hazard when Material Safety Data Sheet Iron Powder/ dust, CIPMS, ZIVMS200 ChemicalStore. Keep away from ignition source and open fire. The evaluation is performed by classifying each chemical based on published toxicological or other data to determine its physical and health hazards. 107-83-5. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Jan 31, 2019 Classification of the substance or mixture Health = 1. The main health hazard associated with releases of this gas is asphyxiation, by displacement of oxygen. B-23 B. Hexanes. 1200 and OSHA Form 174 IDENTITY AND MANUFACTURER'S INFORMATION Start studying Hazards. In general, anything done to reduce the event of a fire or reduce the spread of a fire improves the safety in the laboratory. 1. This Safety Data Sheet is prepared to comply with the United States Occupational Safety and Health Administration (OSHA) Hazard Communication Standard (29 CFR 1910. Simultaneous exposure to the vapors of n-hexane and methyl ethyl ketone or methyl isobutyl ketone above the recommended workplace limits increases the risk of adverse effects from n-hexane. Contact local health and pollution control officials in the event of a chemical fire or spill. The Hazard fields include special hazard alerts, air and water reactions, fire hazards, health hazards, a reactivity profile, and details about reactive groups assignments and potentially incompatible absorbents. Use personal protective equipment as required. Aldrich - 362832 Sigma-Aldrich Corporation www. -. Handling and Storage Protect against physical damage. The Exposure Profile Rating is calculated by the (Toxicity Rating) x (Exposure Rating) x (Time Rating). Specific Method(s) of Fire Fighting: Use water spray to cool fire-exposed containers. At a minimum, Self-Contained Breathing Apparatus and Fire-Retardant clothing must be worn. MATERIAL SAFETY DATA SHEET REACTIVITY DATA STABILITY Stable CONDITIONS CONTRIBUTING TO UNSTABILITY Heat INCOMPATIBILITY (MATERIALS TO AVOID) Mg, strong acids, may act as oxidant HAZARDOUS DECOMPOSITION PRODUCTS Not known HAZARDOUD POLYMERZATION Will Not Occur CONDITIONS TO AVOID Avoid creating dusts, air & moisture sensitive. Mexico. An example is shown to the right. Outside or detached storage is preferred. H331 Toxic if inhaled. product may produce a floating fire hazard as it floats on water. HARMFUL OR FATAL IF SWALLOWED. · Results of PBT and vPvB 110-54-3 n-hexane. Store in tightly closed containers (preferably under nitrogen atmosphere). Explosion. 0 h Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 3,878. **SEE SECTION IV. 31 OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable. Health Rating: 3 - Severe (Life) HEXANE 11/20/08 2:19 AM sunlight and any area where the fire hazard may be acute. 1200 (OSHA Hazard Communication Standard) and Canadian WHMIS Regulations. Seek medical advice if areas with intrinsically safe electrical classification. 2-MODERATE. National Fire Protection Association (NFPA 704M Label). Consult a physician. As a gas, it will act as a simple asphyxiant and present a significant health hazard by displacing the oxygen in the atmosphere. We offer the broadest range of storage capacities for your biological products with the most advanced vacuum technology. Red: Fire Hazard Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Classification. The objective of this program is to SECTION 5 – Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. com Heating may cause a fire In contact with water releases flammable gases which may ignite spontaneously May cause fire or explosion; strong oxidizer Hexane | C6H14 | CID 8058 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards n-Hexane Revision Date 19-Jan-2018 Component CAS-No Weight % Hexane 110-54-3 >95 4. Other Information NFPA Ratings: Health: 1 Flammability: 3 Reactivity: 0 Label Hazard Warning: DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. 25 - 35%. Natural gas condensate. Move out of dangerous area. Vapors may form an explosive mixture with air. containers with water from unmanned hose holder or monitor nozzles until well after fire is out. This Fact Sheet is a summary of available information regarding the health hazards that may result from exposure. EC-No. Quantitative Fire Hazard. Chronic (long- Highly flammable liquid and vapor. Use foam, dry chemical, or carbon dioxide. 9 - 11. Stay away from the ends of tanks. Emits toxic fumes under fire conditions. CAUSES IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT. 5 SECTION V - OPTIONAL HAZARD RATINGS IDENTIFICATION HAZARD RATING 4-EXTREME 3-HIGH 2-MODERATE 1-SLIGHT 0-INSIGNIFICANT **SEE SECTION IV National Fire Protection Association (NFPA) FIRE 3 REACTIVITY 0 . Similarly, installing an automatic fire suppression system (sprinkler system) will reduce the spread of a fire. Use water fog, foam, dry chemical, halon, foam or CO 2. n-Hexane. Move container from fire area if it can be done without risk. Methyl Acetate. Made from 2 mils polyester and a 1 mils gloss polyester laminate. 1. National Fire Protection Association (NFPA) . CONTAINERS MAY EXPLODE IN FIRE. (Class IA) HMIS PHYSICAL HAZARD RATING CHART 0=MINIMAL HAZARD Materials that are normally stable, under fire conditions and will not react to water, polymerize Nov 19, 2014 · Use water in flooding quantities, but water sprays should NOT be used because they may cause the fire to spread; Use fire extinguishers containing foam, dry chemicals and carbon dioxide. Special Firefighting Procedures . You will see hazard diamonds like this on trucks, storage tanks, bottles of chemicals, and in various other places around campus and around town. Dangerous for the environment. PRODUCT AND COMPANY IDENTIFICATION The Hazard Communication Standard (29CFR 1910. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes and clothing. 4=severe. Feb 19, 2013 “In 2009 the total cost of fire is estimated at $331billion, or roughly 2. Sigma-Aldrich - 270997 Page 1 of 7 SIGMA-ALDRICH sigma-aldrich. Separate from oxidizing materials. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. ===== SECTION V - HEALTH HAZARD DATA ===== PERMISSIBLE EXPOSURE LEVEL: SEE SECTION VIII. 30-60 Fire-fighters should wear appropriate protective equipment and self-contained breathing Contaminated absorbent material may pose the same hazard as the. If not breathing, give artificial respiration. During a fire, irritating and highly toxic gases may be generated by NFPA Rating: health: 1; flammability: 3 ; instability: 0;. Show this safety data sheet to the doctor in attendance. 3% of US. Hazardous to the aquatic environment, acute hazard. The liquefied gas can cause frostbite to any contaminated tissue. Pass this information on to employees, customers and users of this product. 3 List of Raw Materials & Primary Hazard Analysis 157 4 Common Assumptions 157 5 Vulnerable Points of Release of Toluene, Hexane ,Xylene & n- Heptane & Consequences 159 6 Fire Scenario 160 7 Toxic release _ Thionyl Chloride 162 8 Safety & Health Guideline for Thionyl Chloride 182 9 Sodium Cyanide Risk Assessment 189 Chemicals and Hazard Rating Systems - The National Fire Protection Association (NFPA) hazard system for chemical materials; Classification of Gases - Oxidizers, Inert and Flammable gases; Dust Explosions - Critical Temperatures and Concentrations - Critical temperatures and concentration parameters for substances like coal, zinc, uranium and more Synonyms : n-Hexane Formula : C 6 H 14 Molecular Weight : 86. Stay upwind and out of low areas where fumes can accumulate. A complex blend of petroleum-derived normal and branched-chain alkane, cycloalkane, alkene, and aromatic Runoff to sewer may cause fire or explosion hazard. MVE, our cryopreservation solution. Naphtha; Low boiling point naphtha. Analysis B. Extinguishing Media: Use water spray to cool fire-exposed containers. hexane 110-54-3 13. 3-HIGH. EFFECTS OF OVEREXPOSURE: Section 5 - Fire Fighting Measures General Information: Containers can build up pressure if exposed to heat and/or fire. HIGHLY FLAMMABLE! This material releases spilled material may create a slipping hazard. Health 2 424 St. Identification of the substance/mixture and of the company/undertaking 1. 5. Weight percent This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. gsmsds. flammable liquids have an NFPA Fire Hazard rating of 4. Exposure Controls and Personal Protection Advice on system design: Provide local exhaust ventilation to maintain recommended P. Cool containers with flooding quantities of water until well after fire is out. -Tel: 1-813-435-5161 - www. N-hexane. Aspiration hazard if swallowed. Use water spray to keep fire-exposed containers cool. n-Hexane is flammable and may be ignited by heat, sparks, and flames. Information Provided UNUSUAL FIRE & EXPLOSION HAZARDS: Vapors are heavier than air and may travel to an ignition source distant from the material handling point. Jan 20, 2003 2. 424 S. 2014 Page 2 of 8 Sebacoyl Chloride 4% in Hexane Created by Global Safety Management, Inc. In a fire or if heated, a pressure increase will occur and the container may burst,. TWA:1800 mg/m3(500 ppm). 3 Effective date : 12. In case of eye contact Safety Data Sheet (HEXANE) PAGE 2 of 9 P202+270+280+281: Do not handle until all safety precautions have been read and understood. As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapor heavier than air and may travel considerable distance to a source of ignition and flash back. 110-54-3. This SDS conforms to U. 0%), HYDROGEN SULFIDE (0. PRODUCT AND COMPANY IDENTIFICATION Product Identity: BT PRIMER Water and water spray may cool the fire but may not extinguish the fire. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. -based National Fire Protection Association (NFPA) for indicating the health, flammability, reactivity and special hazards for many hazardous chemicals through the use of the NFPA 704 Diamond. DOT Classification. Monitor arterial blood gases in cases of severe aspiration. Product will float and can be reignited on surface of water. dust explosion hazard. IMPORTANT: Read this SDS before handling and disposing of this product. We offer Hexane DOT Placards and Signs at best prices. The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. Apr 25, 2017 Category 3. Fire-fighting equipment/instructions Move containers from fire area if you can do it without risk. Keep unnecessary and unprotected personnel from entering the hazard zone. If inhaled If breathed in, move person into fresh air. If involved in a major fire, they should be sprayed with water to Feb 11, 2010 · Hazardous Substances Safety - The Fundamentals - Solvents, Chemicals, Fuels, Fire and Explosion Rating is available when the video has been rented. Telephone Telephones are located near the entrance to the labs. Dec 22, 2017 hexane; normal-Hexane; Hexyl hydride; n-Hexylhydride; Classification of the Runoff to sewer may create fire or explosion hazard. com Heating may cause a fire In contact with water releases flammable gases which may ignite spontaneously and precautions for firefighters Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. The list is by no means complete, and should only be used as a guide. Extremely flammable liquid and vapor. Hazards. EFFECTS OF OVEREXPOSURE: * - chronic health hazard hazard rating and rating systems (e. Fire hazard : Highly flammable liquid and vapor. Vapor may cause flash fire. 0 Revision Date 04/19/2012 Print Date 11/20/2012 1. Overexposure to n -hexane may cause progressive and potentially irreversiblen damage to the peripheral nervous system, particularly in the arms and legs. Learn vocabulary, terms, and more with flashcards, games, and other study tools. Foam, Dry chemical, Carbon dioxide (C02) Water and water fog can cool the fire but may not extinguish the fire. Eliminate all sources of ignition. Keep all sources of ignition and hot metal surfaces away from spill/release if safe to do so. n-Hexane is sometimes used as a denaturant for alcohol, and as a cleaning agent in the textile, furniture, and leather industries. Safe Storage and Disposal of Hexane Designed to stick to oily, greasy or irregular surfaces. further information: the information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. com Material Safety Data Sheet Version 5. The liquid will rapidly boil to the gas at standard temperatures and pressures. Butyl Alcohol. Propyl Acetate. Advice for firefighters BEI=2,5-hexadione in urine, sample at end of shift at workweeks end, 5 mg/g creatine. May be harmful if inhaled. Fire Alarm Manual Pull Station A fire alarm pull station is located outside the MATERIAL SAFETY DATA SHEET Trade Name: Virginia Solvent 4/1 gal MSDS NO. 1 Product identifier Trade name/designation Hexane, Universal Chromatography Grade Product No. Category 2. Let the fire burn. com 8. Section 1 - Chemical Product and Company Identification Aspiration hazard if swallowed. Safety Data Sheet P-6228. Anne APR, Central Marin Office Regulatory Reform (Fire Safety) Order 2005 RR(FS)O5 (or Fire (Scotland) Act 20056). 5 mg/l - 96. 0005- 1. 1200) Label Elements Signal Word Danger Hazardous Areas Classification - North America - North American hazardous locations classification in classes, divisions and groups; IP - Ingress Protection Rating - IP - Ingress Protection rating is used to specify the environmental protection - or electrical enclosure - of electrical equipment there is a fire. The National Institute of Occupational Safety and Health (NIOSH) has established a recommended exposure limit for hexane of 50 ppm for a 10-hour work day or 40-hour work week. The information contained herein is based on data available as of Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. Specific hazards GHS: Classification. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Crude oil may contain variable amounts of benzene and n-hexane. Toluene. Contain and recover liquid where possible or dilute with water or use alcohol-resistant foam to reduce fire hazard. Section 5 - Fire Fighting Measures General Information: Containers can build up pressure if exposed to heat and/or fire. If involved in a fire, it will support combustion. Other Effects Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 1200) and the PEOSH Hazard Communication Standard (N. Acrylonitrile. 6. Vapours may form explosive mixtures with air. EXPLOSIVE LIMITS (% BY VOLUME IN AIR) 0. Section 6 - Accidental Release Measures PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. Spencer street Dalton, GA 30721 (800) 424-9300 (CHEMTREC) 1-(800) 228-4583 (Product Information) 4/29/2005 8/6/2012 SECTION 2 HAZARD IDENTIFICATION OSHA Hazards The hazard identification signal is a color-coded array of four numbers or letters arranged in a diamond shape. FIRST AID MEASURES General advice Consult a physician. Not a DOT  Jun 1, 2015 Pay attention to the fire and health hazards caused by the product. Containers of n-hexane may explode in the heat of the fire and should be moved from the fire area if it is possible to do so safely. T. Simultaneous exposure to the vapors of n-hexane and methyl ethyl NFPA 704 RATINGS and ID NUMBERS for COMMON HAZARDOUS MATERIALS Blue (Health) Red (Fire) Yellow (Reactivity) White UN/NA# Acetone 1 3 0 1090 Acetylene 0 4 3 1001 Alcohol, Ethyl 0 3 0 1170 Alcohol, Methyl 1 3 0 1230 Ammonia, Anhydrous 3 1 0 1005 Antifreeze (Ethylene Glycol) 1 1 0 1142 Butane 1 4 0 1011 Calcium Hypochlorite 3 0 1 OX 2880 SAFETY DATA SHEET Cat# K216-50 Lipid Extraction Kit (Chloroform Free) SDS DATE: Sep 15, 2105 PAGE 3 OF 7 P331 Do NOT induce vomiting. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Paul Street Protection: A-Goggles, B-Goggles & gloves, Fire 3 Rochester, NY 14605 C-Goggles, gloves, & protective wear. IB tert-Butyl Alcohol Building Construction – Fire Ratings o. Hazard: 0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme. Ensure adequate ventilation. Withdraw immediately in case of rising sound from venting safety device or any MATERIAL SAFETY DATA SHEET - CALIBRATION CHECK GAS 3 PRODUCT NAME: HEXANE (0-0. 5%), BALANCE NITROGEN 5. 341SB Page 4 of 7 Respiratory Protection: The use of respiratory protection depends on vapor concentration above the time-weighted TLV. Beware of accumulation of gas in low areas or 2008 Emergency Response Guidebook Information. Cool containers with flooding quantities of water until well after fire is out. Keep unnecessary people away, isolate hazard area and deny entry. Hexane. 100 n-Hexane. The NFPA diamond is designed to give general hazard information for chemicals. PRODUCT AND COMPANY IDENTIFICATION . 9950 Revision Date: 09/25/2007 Page 1 of 9 NFPA 704 (Section 16) EMERGENCY OVERVIEW DANGER! EXTREMELY FLAMMABLE - EYE AND MUCOUS MEMBRANE IRRITANT - EFFECTS CENTRAL NERVOUS SYSTEM - HARMFUL OR FATAL IF SWALLOWED - ASPIRATION HAZARD High fire hazard. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Fire and explosion hazard CAUTION: reignition may occur. 025%, OXYGEN (0. (This is the opposite order from the GHS Hazard Categories. 18 g/mol CAS-No. Cool fire-exposed containers with water. CODE APPROACH TO FLAMMABLE LIQUIDS HAZARDS. Short-term In the event of a hexane fire outbreak, take the following actions: Stop discharge of the  Hexane. · Other hazards. Flammable vapor may spread away from a spill. They are often used for surface cleaning and product formulations due to being extremely ignition resistant. Hazardous to the aquatic environment, long-term hazard. (CAS No) 108-88-3 *In accordance with paragraph (i) of the OSHA Hazard Communication Standard (29 to be typically present in levels much less than 1% for classification. . FIRST-AID MEASURES GENERAL INFORMATION: RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO THIS GAS MIXTURE WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. Runoff to sewer may create fire or explosion hazard. SECTION 3 - HAZARD IDENTIFICATION NOTE: Repeated and prolonged overexposure to the mixture of solvent(s) Hexane - Acute: Ingestion of hexane can cause nausea, vomiting, stomach pain, and diarrhea. 48%), CARBON MONOXIDE (0. 2. Fire Hazard Practically insoluble in carbone tetrachloride, hexane, and chloroform. ALWAYS stay away from tanks engulfed in fire. OSHA, CMA, ANSI, Canadian WHMIS, Australi an WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and Europe an Union REACH Regulations been no reports of human sterility or other reproductive toxicity associated with n-hexane exposures. BDH24575 (VWR International) S ubstance name Hexane (mixture of isomers) NFPA Hazard Rating HMIS Hazard Rating n-Hexane 110-54-3 3 – 10 500 ppm 50 ppm REL: 50 ppm 311/312 HAZARD CATEGORIES: Fire Hazard, Acute Health Hazard Jun 04, 2019 · * - chronic health hazard hazard rating and rating systems (e. Click on the hazards/colors for the specific hazards represented by the numbers. HMIS Hazard Ratings spread material. H-Codes Hazard assessment codes - The codes have the form Hnxx where H stands for "hazard statement"; n=2 for physical hazards, n=3 for health hazards, and n=4 for environmental hazards; and xx is a sequential numbering scheme. FIRE FIGHTERING Hexane . 3. PRODUCT AND COMPANY IDENTIFICATION MATERIAL SAFETY DATA SHEET December 2010 Page 1 of 9 Rev 2 Prepared to U. g. Environmental n-Hexane. MSDS# 89589. Hazard classification Use a fire fighting agent suitable for the surrounding fire. The vapor may be an explosion hazard. • Numbers are used to CLASSIFY hazards to determine what label information is required. Little Pro on 2016-01-06 Views: Update:2019-11-16. SARA 304 Emergency Release Notification Chemical Identity RQ HEXANE 5000 lbs. Move containers from fire area if this can be done without risk. LARGE FIRE: Water  Apr 6, 2015 "This reagent is generally a mixture of several isomers of hexane (C6H14), Classification of the substance or mixture Fire hazard. Clear fire area of unprotected personnel. Areas with possible fire or explosion risks due to explosive atmospheres and/or petrol, hexane, paint solvents or gases and vapors of equivalent hazard. Contact supplier immediately for specialist advice. -16 (3). The National Fire Protection Association (NFPA) has assigned n-hexane a health hazard identification code of 1 (slight) and flammability code of 3 (serious) (NFPA 1994). (Petroleum). FIRE FIGHTING EQUIPMENT: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full Hazard-determining components of labeling: Glutaraldehyde Hazard statements H314 Causes severe skin burns and eye damage. Oct 17, 2017 · Methanol, Acetone, Hexane, Cyclohexanol, and Toluene combustion reactions Rating is available when the video has been rented. Choose from Hexane Labels compliant with ANSI or NFPA. Coming in direct contact with a hazard or chemical in a n—Hexane 110—54—3 5 This material fits the EPA Hazard Category definition of Immediate (Acute) and Delayed (Chronic) Health Hazards and Fire Hazard under SARA Sections 311, 312. Water will not cool hexane below its flash point. 5 - 10 During fire, gases hazardous to health may be formed. J. Based on available data the classification criteria are not met. Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious;. Substance is non-combustible. 0 - 3 Runoff to sewer may create fire or explosion hazard. Nov 19, 2014 Health Hazards Associate with Hexane. Hazard categories X Acute (Immediate) X Chronic (Delayed) X Fire Reactive Pressure Generating SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. 7. MATERIAL SAFETY DATA SHEET Gasoline, All Grades MSDS No. Also, measure n-hexane in expired air. Neurotoxicity: n-Hexane is a mild irritant and CNS depressant in acute exposure, but its principal effects MATERIAL SAFETY DATA SHEET NAPHTHA Page 2 of 14 2 / 14 drowsiness, headache, and similar narcotic symptoms, but no long-term effects. Explosion: Above flash point  The National Fire Protection Association (NFPA), in section 704 of the National Fire Code, specifies a A value of zero means that the material poses essentially no hazard; a rating of four indicates extreme danger. <br />1. Jul 9, 2013 This material is considered hazardous by the OSHA Hazard n-hexane. Benzene, cyclohexane. Use water spray to disperse vapors. NFPA Hazards Rating of Chemicals. 100%. (CAS No) 110-54-3. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. FIRE AND EXPLOSIVE HAZARDS Can form flammable mixtures with air and flash at room temperature. Exposure to N-hexane at concentrations considerably higher than the  Nov 8, 2017 Classification of the substance or n-hexane. 1 This recommended practice applies to those locations where flammable gases or vapors, flammable liquids, or combustible liquids are processed or handled; and where their release into the atmosphere could result in their ignition by electrical systems or equipment. com Page 2 of 6 Health Hazard: 3 Fire : 3 Reactivity Hazard: 0 Potential Health Effects Inhalation Vapours may cause drowsiness and dizziness. Use on machinery, doors, IT equipment, concrete. EXTINGUISHING MEDIA Dry Chemical, carbon dioxide, and foam. MATERIAL SAFETY DATA SHEET This MSDS complies with OSHA Hazard Communication 29 CFR 1910. Inside storage should be in a standard flammable liquids storage room or cabinet. Isopropanol. Will burn if involved in a fire. 0. Cool containers with water spray until well after the fire is out. : 1 1. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. Hexane poses a very dangerous fire and explosion hazard when exposed to heat or flame (Sax, 1989). Chronic Exposure: Long-term exposure may cause effects to specific organs, such as to the liver, MANUFACTURER MATERIAL SAFETY DATA SHEET HAZARD RATING Castle Products, Inc. Water spray may be used to keep fire exposed containers cool, dilute spills to nonflammable mixtu res, protect personnel attempting to stop leak and disperse vapors. MATERIAL SAFETY DATA SHEET CRUDE OIL Print Date: 01/01/2002 ***FOR “DISCLAIMER OF LIABILITY”, SEE THE STATEMENT ON LAST PAGE*** Page 1 of 7 IMPORTANT: Read this MSDS before handling and disposing of this product and pass this information on to employees, Extremely flammable. 2. 4. The Hexane Flame Slide - Duration: FIRE OR THERMAL DECOMPOSITION Carbon Dioxide and/or Carbon Monoxide EXPLOSIVE LIMITS (% BY VOLUME IN AIR) 0. CAS Number, UN/NA Number, DOT Hazard Label, USCG CHRIS Code SMALL FIRE: Dry chemical, CO2, water spray or regular foam. In case of fire and/or explosion do not breathe fumes. Keep people away. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. LB-1592-091 · n-Hexane NFPA   NFPA Hazard Rating System. Fire = 3. Association (NFPA) assigned hexane a flammability rating of 3, meaning that it is a severe fire hazard. M th l. Section 1. Reproductive Hazard f n-Hexane may damage the testes (male reproductive glands). It is slowly being replaced with other solvents. JP-4 (jet aviation fuel). Dike and collect water used to fight fire. Store in tightly closed containers Hazard Symbols: XN F N Risk Phrases: 11 38 48/20 51/53 62 65 67 Section 3 - Hazards Identification EMERGENCY OVERVIEW Danger! May be harmful if absorbed through the skin. 3. Chemical ingredients are listed on the T SCA inventory. If this is not possible, cool fire exposed containers from the sides with water until well after the fire is out. The Environmental Protection Agency (EPA) has listed them as an acceptable alternative for ozone depleting substances in regards to this quality. Vapor may travel considerable distance to source of ignition and flash back. Material Safety Data Sheet Hexane - 7 - Section 16 - Other Information MSDS Creation Date: July 26, 2006 Revision Date: None Information in this MSDS is from available published sources and is believed to be accurate. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910. Aldrich - 79421 Sigma-Aldrich Corporation www. Like gasoline, hexane is highly volatile and is an explosion risk. Materials may ignite spontaneously with air. P370+P378 - In case of fire: Use carbon dioxide (CO2), dry extinguishing powder , alcohol Hexane. 00 straight streams of water. In case of skin contact Wash off with soap and plenty of water. Water may be applied as a fine spray in large quantities when other extinguishing agents are not available. The total cost of 200°F (93°C). CAUTION: Water stream may spread fire. 1200, Regulation (EU) No 453/2010, and described in CLP Regulation (EC) No 1272/2008. 1-SLIGHT. Boil-over may result in a large expulsion of burning oil from the tank, greatly increasing the fire area. Concentration n-Hexane 110-54-3 203-777-6 601-037-00-0 - 4. ▻ n-Hexane can affect you when inhaled  Mar 19, 2015 Chronic hazards to the aquatic environment, category 2. No action shall be taken involving any personal risk or without suitable training. OSHA. Specific Hazard(s): Flammable liquid. Containers may explode in the heat of a fire. Water reactive. Analgesics may be necessary for pain management, there is no specific antidote. Use shielding to protect against bursting containers. Physical Hazard: 0 NFPA Rating Health Hazard: 2 Fire: 3 n-Hexane 110-54-3 SARA 311/312 Hazard : Fire Hazard, Acute Health Hazard, Chronic Health hazard. 5 - 1. sigma-aldrich. Employers are required to train all workers who use materials containing toluene about the health and safety hazards of toluene, how to recognize exposure to toluene, and the protective measures that apply to the use of toluene in the specific work area. A. 1 Product identifier Common name Normal Hexane 97% Synonyms Normal Hexane For small fires, class B fire extinguishing media can be used. Vapors are heavier than air and may travel considerable distance to an ignition source and flash back to source of vapors. 18 toluene 108-88-3 8. Do not eat, drink or smoke when using this product. Dec 11, 2014 n-hexane. 30 OSHA PELs and ACGIH TLVs are listed in Section 8 where applicable. Ventilate area of leak or spill and isolate hazard area. 9 – 11. HAZARD RATING. Contact with combustible materials may cause a fire. Hexane – Chronic General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. If involved in fire, shut off flow immediately if it can be done without risk. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: Hydrogen is a colorless, odorless, flammable gas or a colorless, odorless, cryogenic liquid. Revision  Jan 1, 2002 NFPA Hazard Rating: Fire and. 001- 0. 1200) requires all manufacturers or distributors of any products containing chemicals to evaluate the chemical hazards of the product. Acetone. 2 This recommended practice provides information on specific flammable gases and vapors, flammable Material Safety Data Sheet Page 1 of 6 Overexposure to n-hexane may cause progressive and potentially irreversible Fire Hazard Yes Material Safety Data Sheet Hazard Rating System Classifications: NFPA 2 HMIS 0 /National Fire Protection Association rating identifies hazards a fire emergency FIRE OR THERMAL DECOMPOSITION Carbon Dioxide and/or Carbon Monoxide. A; B; C; D; E; F; G; H; I; J; K; L; M . Mutagenicity: Positive results (chromosomal damage in the bone marrow cells) obtained for rats exposed by inhalation to n-hexane. com Page 5 of 6 Signs and Symptoms of Exposure To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly hexane 110-54-3 27. May accumulate static electrical charges, and may cause ignition of its own vapors. 8030-30-6. Dec 8, 2014 Classification of the substance or mixture n-Hexane. When the potential chemical hazard is unknown, in enclosed or confined spaces, a self contained breathing apparatus should be worn. Hexane can irritate the skin and the eyes. Water runoff can cause environmental damage. In case of eye contact 4=SEVERE HAZARD Flammable gases, or very volatile flammable liquids with flash points below 73° F, and boiling points below 100° F. Hexanes,Normal Hexane; Hexyl Hydride; Hexane 95% Molecular Weight: 86. Use of a direct water stream may Hexane /Acetone 240 Flammable Grit Strip Adhesive UN 1133 Hazard Class 3 Packing Group Il Advanced Adhesive Technologies, Inc. Safety Data Sheet Revision Date: 14-aug-2013 Version No. The fire risk assessment should include, for example, measures to reduce the risk of fire and the risk of spread of fire on the premises and measures in relation to the means of escape from the premises. Overexposure to n-hexane may cause progressive and potentially irreversible damage to the peripheral nervous system, particularly in the arms and legs. Reactivity = 0. HMIS RATING: HEALTH- 2, FLAMMABILITY- 3, REACTIVITY- 0, PERSONAL PROTECTION- B Hexane – Acute: Ingestion of hexane can cause nausea, vomiting, stomach pain, and diarrhea. Guidance on assessing the extent of the hazard is given in the NFPA 497 or NFPA 499 standards published by the National Fire Protection Association for explosive gas or dust atmospheres respectively, or RP 500 and RP 505 standards published by the American Petroleum Institute, and IEC 60079-10-1 or IEC 60079-10-2 standards published by the Consult a physician. GHS hazard statement means a standard phrase assigned to a hazard class and category to describe the nature and severity of a chemical hazard. Incidents Sigma-Aldrich - 439177 Page 1 of 8 SIGMA-ALDRICH sigma-aldrich. Environmental, Health, and Physical Hazard Information . Product Identity: Protecto-Tak . SARA Section 311/312 The following hazard categories apply to this product: Acute health hazard Chronic health hazard Fire hazard Sudden release of pressure SARA Section 313 This product may contain any the following components which may be subject to reporting on a toxic release inventory. 110-54-3 Runoff to sewer may create fire or explosion hazard. Acute (short-term) inhalation exposure of humans to high levels of hexane causes mild central nervous system (CNS) effects, including dizziness, giddiness, slight nausea, and headache. In a fire involving hexane, NFPA recommends the affected area be iso- and precautions for firefighters Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. A value of zero means the chemical presents no hazard while a value of four indicates a high hazard. 1993. 0 Revision Date 04/21/2012 Print Date 05/21/2012 1. Our best adhesive for LSE plastics. Jul 31, 2018 · Additional information regarding the NFPA rating system is available from the National Fire Protection Agency (NFPA) at www. NFPA 704 rating system is a standard system developed by the U. Do not use a direct stream of water. Unusual Fire and Explosion Hazards: Contents under pressure. 5*. FLASH POINT: not flammable when heated. GDP. Explosion hazard in fire situation. This SDS complies with 29 CFR 1910. Little Pro on 2015-12-30 Views: Update:2019-11-16. Combustible liquids are rated as 1, or 2. Spillages of liquid product will create a fire hazard and may form an explosive atmosphere. Mar 11, 2014 GHS Classification in accordance with 29 CFR 1910 (OSHA HCS) n-Hexane Fire Hazard, Acute Health Hazard, Chronic Health Hazard. Long-term Environmental Hazards Classification Unusual Fire Explosion Hazards. Code of Federal Regulations 29 CFR Classification of the substance or mixture Fire hazard. VAPOR MAY CAUSE FLASH FIRE. Material Safety Data Sheet SONNEBORN® 200 ADHESIVE Version 1. SAFETY DATA SHEET This SDS complies with 29 CFR 1910. Other Information Prevent further leakage or spillage if safe to do so. Special Fire Fighting Procedures and Precautions Warning: Flammable. pounds based on the RQ for n-hexane of 5,000 lbs present at less than 60% must be reported to the National HMIS Hazard Rating: Fire Hazard – 4 (severe Open top tanks involved in a fire have a potential for "boil-over" if water or water-in-oil emulsion is at the bottom of the tank. The vapor/gas is heavier than air and will spread along the ground. SECTION 3 – HAZARD IDENTIFICATION NOTE: Repeated and prolonged overexposure to the mixture of solvent(s) listed in Section 2 can result in systemic effects including permanent brain, nervous system, liver, and kidney damage. FIRE-FIGHTING MEASURES These containers hold gas under pressure, with no liquid phase. material safety data sheet arts cleaner (hexane) fire and explosion hazard data flammability as per usa flame projection test Hexane is a colorless, volatile liquid with a faint odor. org. Hexane, n-, 1, 3, 0. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Containers should be bonded and grounded Attached below is a list of common hazardous materials and their CAS (Chemical Abstract Service) numbers, NFPA codes, and hazard codes. This may include self-contained breathing apparatus to protect Wear full fire fighting turn out gear and self contained breathing apparatus operated in the positive pressure mode. We offer Hexane DOT n-Hexane NFPA Chemical Hazard Label. EXPLOSION HAZARDS: Containers can build up pressure if exposed to heat and/or fire. For instance, storing flammables in a proper flammable storage cabinet will reduce the event of a fire. GHS Hazard Statement List. C. Acutely, the most common toxic effects are central nervous system depression and chemical pneumonitis resulting from aspiration into the lungs following ingestion. Unusual Fire or Explosion Hazard: Material is highly volatile and emits vapors which may travel along the ground and be ignited by remote ignition sources. Isopropyl Acetate Class IA & IB flammable liquids have an NFPA Fire Hazard rating of 4. US NFPA Ratings. Cyclohexane. 11- 26. Produced by the US DOT the ERG is designed to aid first responders in quickly identifying specific or generic hazards of materials involved in an incident and protecting themselves and the general public during the initial response phase of an incident. H317 May cause an allergic skin reaction. Can enter lungs and cause damage. NFPA ratings Hazard Hexane (110-54-3) 5000 No No Methylcyclopentane (96-37-7) No No No 14. Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * Chronic 4. Hexane can irritate the skin and eyes. FIRE 3. Sensitive to stati c discharge. Flammable May cause fire or explosion; strong oxidizer Other Non-GHS Classification: 110- 54-3 , n-Hexane, OSHA (PELs) 500 ppm TWA; 1800 mg/m3 TWA. Further guidance about completing a fire risk NFPA Rating and OSHA’s Classification System 0-4 0-least hazardous 4-most hazardous 1-4 1-most severe hazard 4-least severe hazard •The Hazard category numbers are NOT required to be on labels but are required on SDSs in Section 2. Wear protective gloves/protective clothing/eye protection/face protection. 1 Scope. nfpa. Contact with strong oxidizers may cause fire. D10N1EF Revision Date: Date Printed 05/20/2009 Page 1 of 5 1. Hazards Identification Emergency Overview----- DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR. € never use a water jet as this will just spread the fire. 0 - 3 hazard. 1200). 18 Chemical Formula: CH3(CH2)4CH3 n-hexane 3. Precautionary statements P210 Keep away from flames and hot surfaces. some time after exposure to n-Hexane and can last for months or years: Cancer Hazard f According to the information presently available to the New Jersey Department of Health, n-Hexane has not been tested for its ability to cause cancer in animals. Get one now! SANTA ROSA FIRE DEPARTMENT FIRE PREVENTION BUREAU STANDARD NFPA 704 CHEMICAL HAZARD RATINGS NFPA HAZARD RATING INFORMATION FOR COMMON CHEMICALS SPECIAL CHEMICAL HEALTH FIRE REACTITY HAZARD Acetal 2 3 0 Acetaldehyde 2 4 2 Acetic Acid (glacial) 2 2 2 Acetic Anhydride 3 2 2 W Acetone 1 3 0 Acetonitrile 2 3 0 Acetophenone 1 2 0 Links with this icon indicate that you are leaving the CDC website. Chronic effects of VM&P: VM&P contains -hexane. 2014 Page 2 of 7 Hexane (n-Hexane) Created by Global Safety Management, Inc. 3 06/29/2006 Page 2 of 7 Skin : Components of the product may be absorbed into the body through the skin. If this is impossible then take the following precautions: Keep unnecessary people away, isolate hazard area and deny entry. cryogenic form. 0- INSIGNIFICANT. Great products, shipping was very quick! I'll be sure to re-order soon. (Isopropyl alcohol, n- hexane). 110-54- 3. unusual fire and explosion hazards: vapors are heavier than air and may travel to distant sources of ignition and flashback. Special protective actions for fire-fighters: For fires beyond the initial stage, emergency responders in the immediate hazard area should wear protective clothing. Apr 10, 2015 · As opposed to petroleum-based organic solvents, chlorinated options are a minimal fire hazard. Fire Fighting Measures Fire: Flash point: -23C (-9F) CC Hexane 110-54-3 Hazard Summary Hexane is used to extract edible oils from seeds and vegetables, as a special-use solvent, and as a cleaning agent. In this labeling system, the number 4 is associated with higher hazards, and the numbers 1 and 0 with lower hazards. The federal OSHA Hazard Communication Standard (29 CFR 1910. Explosion hazard : May form flammable/explosive vapor-air mixture. Fire Extinguisher Fire extinguishers are located near the lab entrance (B120, Rm 257, 258; B131, Rm 209) or just outside the laboratory door (B120, Rm 260; B131, Rm 113). Class IC flammable liquids are rated as 3. CAUSES IRRITATION TO SKIN, EYES AND 1. Health Hazard. UN Classification of Chemical Hazards UN Hazard Identification System With examples Explosives UN Class 1 - Explosives hexane, acetonitrile 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. What is the WHMIS 1988 classification? What are the most important What are fire hazards and extinguishing media for acetone? Flammable Properties:  Choose from Hexane Labels compliant with ANSI or NFPA. ) Special Fire Fighting Procedures: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. 5 Hexane Pimephales promelas (fathead minnow) - 2. Page 1 of 13 MSDS ± HEXANE MATERIAL SAFETY DATA SHEET (MSDS)- HEXANE SECTION 1 PRODUCT AND COMPANY IDENTIFICATION of fire and explosion hazard and warn them NFPA RATING SYSTEM 23-1 NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) RATING SYSTEM The purpose of the NFPA rating is to advise emergency response personnel via the hazard diamond sticker of hazards they may encounter when entering the room in response to fire or other situations. • In case of fire – Deny any unnecessary entry into the area. E. UNUSUAL FIRE & EXPLOSION HAZARDS: Vapors are heavier than air and may travel to an ignition source distant from the material handling point. -26 (-15). -18 (0). Xylene Note that contaminated clothing may be a fire hazard. hexane fire hazard rating